Prismatic vs Pouch VS Cylindrical LiFePO4 Batteries Cells

15 Jul.,2024

 

Prismatic vs Pouch VS Cylindrical LiFePO4 Batteries Cells

Choosing the right lithium-ion phosphate battery for your RVs, boats, or solar homes can be challenging without knowing the differences in battery construction, performance, and durability. Therefore, it's essential to understand the significance of battery cell packing type when selecting a Lithium Iron Phosphate (LiFePO4) battery. The cell packing type plays a vital role in the battery's overall performance and longevity, making it a crucial factor to consider.

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In this blog, we'll explore why understanding battery cell is critical when choosing the right battery for your specific application, and take an in-depth look at cylindrical, pouch and prismatic LiFePO4 batteries.

Part 1: Types of LiFePO4 Battery cells

1. Cylindrical LiFePO4 cells

These cells typically have a metal casing that protects the positive and negative electrodes, which are wound into a spiral or cylindrical shape. Cylindrical LiFePO4 cells come in various sizes, with some of the most common being , , and .

Cylindrical LiFePO4 cells are commonly used in applications where high energy density and long cycle life are required, such as electric vehicles, power tools, and home energy storage systems. They are also well-suited for use in parallel and series arrangements to create larger battery packs with higher voltage and capacity.

LiTime 48V 30Ah Lithium Golf Cart Battery Size in GC2 is build by cylindrical LiFePO4 cells.

Like other LiFePO4 batteries, cylindrical LiFePO4 cells offer several advantages over other battery chemistries, including high energy density, long lifespan, and excellent safety characteristics. However, they do require careful handling and charging to ensure optimal performance and longevity.

Advantages of Cylindrical Cells

  • Robustness: Cylindrical cells are known for their robustness and durability, making them suitable for applications where mechanical stress is a concern.
  • Thermal Management: They offer relatively better thermal management due to their shape, which allows for efficient heat dissipation.
  • Widely Available: Cylindrical cells are widely available and have been extensively used in consumer electronics and electric vehicles like golf carts.

2. Prismatic LiFePO4 cells

Prismatic LiFePO4 batteries are named for their rectangular, prism-like shape. They typically have a hard plastic casing that protects the battery cells and can be stacked together to create larger battery packs. Prismatic LiFePO4 batteries are commonly used in electric vehicles, solar power systems, and other applications that require high-performance and long life.  Most of LiTime LiFePO4 batteries are made of prismatic cells.

Advantages of Prismatic Cells

  • Space Efficiency: Prismatic cells have a rectangular or square shape, which allows for efficient use of space in battery packs, making them ideal for certain applications with specific space constraints.
  • Stackability: They can be stacked more easily than cylindrical cells, simplifying the construction of larger battery packs.
  • Ease of Assembly: Prismatic cells can be easier to assemble into battery modules or packs due to their uniform shape.

3. Pouch LiFePO4 cells

These cells are thin and flexible, making them ideal for use in portable devices. They offer higher energy density than other types of LiFePO4 cells but are still highly reliable and long-lasting.

Advantages of Pouch Cells

  • Flexibility: Pouch cells are lightweight and flexible, making them suitable for applications where space and weight are critical factors.
  • Customization: They can be manufactured in various sizes and shapes, allowing for greater design flexibility.
  • Cost-Effectiveness: Pouch cells are often cost-effective to produce and can offer a good balance between performance and cost.

Part 2: Pouch LiFePO4 Battery VS Prismatic LiFePO4 Battery

A pouch LiFePO4 battery is a type of rechargeable battery that uses lithium iron phosphate (LiFePO4) as the cathode material and a flexible Aluminum Laminate film as the battery casing.

Compared to traditional cylindrical or prismatic LiFePO4 batteries, pouch LiFePO4 batteries have a higher energy density, are more flexible and lightweight, and can be customized to fit a variety of shapes and sizes.

Pouch LiFePO4 batteries are commonly used in applications where high energy density, high power output, and long cycle life are required, such as electric vehicles, solar power systems, and portable electronic devices. They are also considered to be safer and more environmentally friendly than other types of lithium-ion batteries, as they are less prone to overheating and do not contain toxic heavy metals.

Prismatic LiFePO4 batteries have a rigid, rectangular shape and are typically made up of stacked electrode layers that are separated by a thin polymer film&#; typically used in larger applications that require more power and capacity, such as  electric vehicles, solar power storage systems, and backup power supplies for buildings.

Aspect Cylindrical LiFePO4 Cells Pouch LiFePO4 Cells Prismatic LiFePO4 Cells Robustness Robust Moderate Moderate Thermal Management Good Moderate Moderate Flexibility Limited High Limited Customization Limited High Limited Space Efficiency Moderate High High Stackability Limited Limited High Ease of Assembly Moderate High Moderate Cost-Effectiveness Moderate High Moderate Widely Available Yes Yes Yes Application Examples Consumer electronics, EVs Portable electronics, EVs EVs, Energy storage

2.1 Pouch Cell Swelling? Satety Concerns of Pouch Cells

Pouch cell swelling, also known as "pouch ballooning," is a phenomenon commonly observed in lithium-ion pouch cells. It occurs due to several factors related to the cell's construction and operation:

  • **Gas Formation:** During the normal operation of a lithium-ion cell, especially during charging, a small amount of gas can be generated as a byproduct of the electrochemical processes occurring within the cell. This gas primarily consists of oxygen and hydrogen, which can lead to the buildup of internal pressure.
  • **Electrolyte Decomposition:** Over repeated charge-discharge cycles, the electrolyte within the cell can undergo decomposition. This decomposition can produce gases, such as carbon dioxide, which contribute to the internal pressure buildup.
  • **Formation of Solid-Electrolyte Interphase (SEI) Layer:** The formation and growth of the SEI layer on the electrodes during cycling can also contribute to the generation of gases within the cell, leading to increased internal pressure.
  • **Volume Changes in Electrodes:** During charging and discharging, the electrodes within the pouch cell undergo volume changes as lithium ions are inserted and extracted. These volume changes can lead to mechanical stress on the pouch packaging, potentially causing it to swell.
  • **Heat Generation:** Heat generated during charging and discharging can also contribute to the expansion of the cell components, including the electrodes and the electrolyte, leading to swelling.

The combination of these factors can lead to the expansion of the pouch cell, causing it to swell. Pouch cell swelling can affect the performance and safety of the cell, potentially leading to mechanical stress on the internal components, degradation of the electrode materials, and compromise of the cell's structural integrity.

Although LiFepo4 Pouch Cells are considered safer than other lithium-ion battery technologies, it remains crucial to handle them with care. Choosing a reputable supplier is a key factor to guarantee the cells' quality and reliability. Additionally, following proper handling and storage protocols, minimizing the risk of physical damage or puncture, and conducting regular monitoring for any signs of malfunction are essential practices. Lastly, it's important for customers to plan for the safe disposal or recycling of batteries and prevent exposure to extreme temperatures or moisture.

Ensuring that LiFepo4 Pouch Cells adhere to regulatory standards such as UL, CE, and RoHS is vital. These safety certifications confirm that the batteries meet stringent safety and environmental criteria and have undergone thorough testing and quality control procedures.

All of LiTime LiFePO4 lithium batteries have passed the test of UL, CE, and RoHS.

LiTime 12V 100Ah Mini is made of pouch cells, here's the battery cell drill test. 

Part 3: Applications for Pouch LiFePO4 Batteries

Pouch LiFePO4 batteries are a great choice for outdoor applications because they are durable, reliable, and have a long cycle life. They can withstand extreme weather conditions, making them ideal for use in outdoor environments.

&#; Solar-powered lighting: Pouch LiFePO4 batteries are ideal for powering outdoor solar lighting. They are lightweight, durable, and have a long cycle life. Additionally, they are resistant to extreme temperatures and weather conditions.

&#; Electric vehicles: Pouch LiFePO4 batteries are widely used in electric vehicles (EVs) because of their high energy density, fast charging capabilities, and long cycle life. Outdoor EV charging stations can benefit from these batteries as they can withstand extreme weather conditions.

&#; Backup power for off-grid systems, such as remote weather stations, wireless communication systems, and other outdoor equipment. They are also ideal for powering off-grid homes and cabins.

&#; Marine applications, such as electric boats, yachts, and other watercraft. They are waterproof and resistant to corrosion, making them ideal for harsh marine environments.

&#; For RV and camping applications, Pouch LiFePO4 batteries can be used to power various devices such as lighting, refrigerators, air conditioners, and other electronic devices.

Part 4: Frequently Asked Questions

1. What is a Pouch LiFePO4 battery, and how does it work?

A Pouch LiFePO4 battery cell is typically made up of a thin Aluminum plastic pouch that contains the battery components, including the electrodes, electrolyte, and separator. The pouch is then sealed to prevent leakage and protect the cell from moisture and damage. The battery works by transferring lithium ions between the cathode and the anode during charging and discharging.

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2. What are the advantages of using a Pouch LiFePO4 battery?
The advantages of using a Pouch LiFePO4 battery include long cycle life, fast charging, high energy density, low self-discharge rate, and improved safety features.

3. What is the typical lifespan of a Pouch LiFePO4 battery?
A Pouch LiFePO4 battery can have a lifespan of up to 10 years or more, depending on usage and environmental factors.

4. Can I use a Pouch LiFePO4 battery in cold weather conditions?
Yes, Pouch LiFePO4 batteries can operate effectively in cold weather conditions as they have a better performance than other lithium-ion batteries.

5. Can I overcharge or over-discharge a Pouch LiFePO4 battery?
No. LiTime LiFePO4 batteries have a built-in battery management system that prevents overcharging or over-discharging, ensuring the battery's safety and longevity.

Visit LiTime user-stories and youtube reviews for more information about LiTime batteries.

6. Can I use a Pouch LiFePO4 battery in place of a lead-acid battery?
Yes, Pouch LiFePO4 batteries can be used as a direct replacement for lead-acid batteries in many applications, including electric vehicles, off-grid solar systems, and marine applications.

7. How fast can a LiFePO4 battery charge?
A LiFePO4 battery can be charged at a faster rate than a traditional lead-acid battery, and in some cases, can be charged up to 80% in less than an hour. We suggest you using LiFePO4 battery charger in order to keep the battery in good conditions.

8. How do I store a LiFePO4 battery properly?
It is recommended to store LiFePO4 batteries in a cool and dry place, away from direct sunlight and heat sources. It is also recommended to keep them charged to about 50% of their capacity during storage. 

Conclusion

In summary, when selecting a LiFePO4 battery for specific applications such as RVs, boats, or solar homes, it is crucial to understand the significance of battery cell packing type. Pouch and prismatic LiFePO4 batteries are two different types of cells with their advantages and disadvantages.

Pouch batteries offer higher energy density, flexibility, improved thermal management, and reduced risk of internal short circuits and swelling. They are ideal for portable electronics, solar-powered lighting, electric vehicles, marine applications, off-grid systems, RVs, and camping applications.

On the other hand, prismatic batteries are typically used in larger applications such as electric vehicles, solar power storage systems, and backup power supplies for buildings. The choice between the two depends on the specific needs of the application.

Types of Lithium Batteries: Lithium Cell Format - OneCharge

Main Lithium Battery Pack Components

Currently, there is no one standardized format for a lithium-ion battery. The battery cell format and shape is selected based on the user&#;s needs, which ultimately influences the design of the battery module. The current lithium battery market typically offers a three-tier battery concept to customers: cell, module, pack.

The main lithium-ion battery components usually are battery cells, cell contacting, cell fixation, housing, thermal management and the battery management system (BMS), including its periphery. To learn more about cell design, see Types of Lithium Batteries: Lithium Cell Design.

Furthermore, depending on the cathode material composition, the most common lithium-ion cell chemistries are lithium ferric phosphate, or lithium iron phosphate (LFP), lithium nickel manganese cobalt oxide (NMC), and lithium nickel cobalt aluminum oxide (NCA). To learn more about lithium-ion chemistry, see the Types of Lithium Batteries: Lithium Cell Chemistry.

Cell Shapes

Battery cells are designed in different shapes and form-factors: cylindrical, prismatic and pouch cells. The inner structure, the electrode-separator-compound, are different in terms of the dimensions and the manufacturing processes used.


Prismatic lithium cell

Prismatic lithium cell


Pouch lithium cell

Pouch lithium cell


Cylindrical lithium cell

Cylindrical lithium cell

Cylindrical Cells

Cylindrical cells consist of sheet-like battery anode, cathode, and separator that are sandwiched, rolled up, and packed into a cylinder-shaped can. This type of cell is one of the first to be mass-produced and is still very popular. Cells feature multiple rows with the arrester being on opposite sides. They are adhesive connected with busbars by welding technology and are optionally wire bonded. In this case, no support plates are necessary. Cylindrical cells have to be fixated into a battery module or pack by rigid spacers, spacer strips, or mounting brackets. Additionally, glue can be used as the primary fixation of cylindrical cells. These fixings add additional weight and complexity to the battery pack.

Pouch Cells

Pouch cells do not have a rigid outside can and use a sealed flexible foil as the cell container. The electrode and separator layers of a pouch cell are stacked. With pouch cells, the designer should allocate enough space for possible swelling. Modules with pouch cells show single-rowed cells with the arresters being positioned either on the same or the opposite sides. Pouch cells can be connected by adhesive bond welding and in either tab-to-tab or tab-to-busbar bridges without support. Also, they may be connected by a form-fit connection using screws and busbars as a bridge without any support plates.

For pouch cells, cell frames are often used as primary fixation. In this case, the cells are inserted, redundantly sealed and flexibly tensioned. The spaces between the cells could even be additionally used for a cooling system. Optionally, pouch cells may even be glued.

Prismatic Cells

Prismatic cells consist of large sheets of anodes, cathodes, and separators sandwiched, rolled up, and pressed to fit into a metallic or hard-plastic housing in cubic form. The electrodes can also be assembled by layer stacking. Lithium prismatic cells feature either single-row or two-row modules and the arresters are always on the same side regardless of the row.

Prismatic cells are either adhesive-bonded by welding, with busbars and support plates or traction / form-fit connected with screwing/] or latching as joining technology and hole-busbars as a bridge. Lastly, prismatic cells can be fixed by gluing. This requires a light and elastic joining medium to avoid air pockets.

Technical Comparison

Cylindrical cells are usually produced in standard models in terms of size. One common size is the type (18 mm diameter, 65 mm height). This type has a total mass of about 45 grams and can support a capacity of about 1.2 to 3 Ah depending on the technology employed.

Pouch cells have a soft construction that requires the use of a support structure with these cells. Additionally, the cell should not be placed near sharp edges. The approximate cell capacity range is 2.5-8 Ah, and the approximate weight is 75-225 g.

Prismatic cells are manufactured with a capacity ranging from several Ah targeted for laptops and cell phones to hundreds of Ah designed for EV applications. The weight range is 0.8-5.2 kg.

Comparison of Cylindrical, Pouch and Prismatic Battery Cells

  Advantage Disadvantage Cylindrical cell
  • Batteries are suited for automated manufacturing.
  • Easier pack thermal management (space between the cells lets the coolant easily circulate within a battery pack).
  • Mechanical stability (the round shape of the battery distributes the internal pressure from side reactions over the cell circumference almost evenly).
  • Low packaging density of cylindrical cells (the cell&#;s circular cross-section does not allow full utilization of the available space).
  • High-capacity batteries with a large number of cylindrical cells require excessive support and contactors system, thus increasing the complexity and weight of the battery.
Pouch cell
  • Lowest weight (among all cell types).
  • Flexible cells (can easily fit the available space of a given product).
  • Need to customize most pouch cells.
  • Need to protect against external impacts or punctures; not a good fit for industrial and machinery use.
Prismatic cell
  • Optimal utilization of pack and battery compartment space.
  • Cells are not subject to swelling.
  • Highest Ah nominal capacity and kWh energy (battery watt-hours).
  • Higher overall battery energy density (compared to cylindrical cells).
  • Lighter overall LIB weight compared to batteries with cylindrical cells (no higher strength stainless steel as a battery shell).
  • More potential stress for parts of the electrode and separator sheets that are close to the container corners.
  • Cells can be more expensive to manufacture.

Applications

Cylindrical cells are widely used in power tools, toys, lamps, the automotive industry, e-bikes and some portable mobile energy systems.

Pouch cells are widespread in smartphones, drones, laptops, wearable devices, etc.

Finally, prismatic cells are widely used in electric vehicles, including off-highway industrial trucks and different types of forklifts, communication-based stations, grid energy storage, medical fields, etc.

Prismatic Cells are the Best Choice for Forklift Batteries

The differences in battery technology today allow customers to choose the best fit for their applications. Thus, lithium prismatic cells are the preferred technology for material handling equipment (MHE):

Hundreds of Ah nominal capacity. The technology provides the best ratio of power and energy per volume unit. This is especially important in the high-capacity, high-current and relatively low voltage batteries used in MHE.

Optimal utilization of available pack space. There are no space cavities between the cells. This allows maximum capacity for the battery pack, and still have enough room to accommodate for required extra weight, sealing, heater, internal charger or other battery upgrades within the battery compartment&#;s limited area.

Contacts are strong enough for reliable bus-bars connection. This is a hugely important safety factor with high vibration operations, especially in cushion-tire type lift trucks.

Flexible battery weight. LIB pack weight is not a limitation for most of the MHE in terms of its range per one charging (unlike passenger EVs). Forklifts operate mostly near their charging stations and their batteries are often engineered as a counterweight.

Are you interested in learning more about 24 volt forklift battery for sale? Contact us today to secure an expert consultation!