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Caution must be used when using tin / bismuth alloys. It is dangerous to mix tin / bismuth with lead containing alloys. Tin, bismuth, and lead can form a very low melting combination that melts around 95 °C. This could potentially lead to solder joint failure due to natural heating of the assembly during use.
Tin / bismuth alloys are safe to use in combination with other lead free tin-based alloys. In some cases surface mount assemblies are made with SAC305 on the first side and tin / bismuth on the second side. The low reflow temperature for tin / bismuth minimizes intermetallic growth in the SAC305 solder joints and allows for soldering of thermally sensitive components.
Definitelymix Pb solder with the low temp Bismuth-based solders (also there is the different melting point issues, but the alloy that forms is awful). Joint becomes very brittle due to strong intermetallic growth and easy to break with even what I could consider moderate force. For example, with the right (or wrong) mix of solder and a decent grip, I can pull SMD aluminium polymer caps off the board with my bare hands.I'm pretty sure remember reading a super old IBM article where they investigated this Bi/Pb mix for some temperature sensitive parts in a mainframe, and it was a disaster. Can't find the article now thoughAlso from http://www.surfacemountprocess.com/low-temperature-lead-free-solder-paste.html
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